Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on. The combustion of biomass, in this case demolition wood, has been investigated in a grate combustion multifuel reactor. In this work a temperature range of 850–1000 °C is applied both for staged air combustion and nonstaged combustion of biomass to investigate the effects of these parameters on the emission levels of NOx, N 2O, CO, hydrocarbons (C xH y) and different other components. The composition of the flue gas is measured by four advanced continuous gas analyzers including gas chromatograph (GC), two Fourier transform infrared (FTIR) analyzers, and a conventional multispecies gas analyzer with fast response time.
Influence from process parameters on void formation in resin transfer molding. On high temperature aerosol formation in fixed bed combustion of woody biomass pellets. The influence of air distribution rate on particle emissions in fixed bed.
The experiments show the effects of staged air combustion, compared to nonstaged combustion, on the emission levels clearly. A NOx reduction of up to 85% is reached with staged air combustion. An optimum primary excess air ratio of 0.8–0.95 is found as a minimizing parameter for the NOx emissions for staged air combustion. Air staging has, however, a negative effect on N 2O emissions. Even though the trends show a very small reduction in the NOx level as temperature increases in nonstaged combustion, the effect of temperature is not significant for NOx and C xH y, neither in staged air combustion or nonstaged combustion, while it has a great influence on the N 2O and CO emissions, with decreasing levels with increasing temperature.
The aim of this study is to characterize and burn out three olive pomace samples in a fixed bed boiler. These products are: raw olive pomace (R.O.P), exhausted olive pomace (E.O.P), and deoiled olive pomace (D.O.P). Before their combustion, they have been characterized using different analyses: proximate, ultimate, and thermogravimetric. So, proximate analysis illustrated that raw olive pomace contains volatile matter (74.2%), fixed carbon (20.2%), moisture (7.51%) and ash (2.8%). Next, ultimate analysis showed that R.O.P has important content percentages of carbon and oxygen (48.2% and 44.3% respectively).
Furthermore, thermogravimetric analysis proved that the weight loss corresponding to the burnt volatile matter (VM) is ranging between 65% and 75% for all these biomasses. During the combustion of (R.O.P) and (E.O.P) samples, which is compared to that of wood sawdust, ignition propagation and char oxidation were observed. Moreover, effects of olive pomace particle size on temperature distributions at different combustor device positions were highlighted. The maximum temporal average temperature was reached with the smaller particles. Finally, the flue gas composition (O 2, CO, CO 2, NO x, SO x) has been measured and it has shown that the emissions of nitrogen oxides (NOx) are very low and sulphur oxides (SO x) are negligible. The transition from fossil fuels to renewable energies, such as wind, solar and biomass, has become one of the key energy issues in terms of renewable, clean resources, and important reduction in carbon emissions 1.In recent years, Morocco has adopted an energy transition strategy whose objective is to generalize and secure supply and access to clean energy to preserve the environment 2.
Nevertheless, biomass remains a neglected energy source despite of its abundance in Morocco, especially, in the form of agriculture and forestry wastes (olive pomace, argan shells, bagasse, date palm trunk, wood chips.).The high energy potential of biomass takes a large part in scientific research, particularly in the field of renewable energies. In 2009, Khan et al.
3 provided more data concerning the impact of biomass properties on the combustion process and emission characteristics. They concluded that a lot of efforts are needed to make biomass economically competitive by comparison with the currently used energies, but they affirmed that there are no insurmountable obstacles for this sustainable energy source.
Moreover, a large diversity of biomass forms constitutes a fertilized field of scientific research that studied separately each variety such as biomass pellets 4-10, pin chips 11 and olive cake 12-26. These studies cover experimental and numerical studies on biomass combustion, synthesis characterization and drying of several kinds of biomasses. Forbes et al. 6 have given physico-chemical characteristics of eight different types of biomass (pine, sitka spruce, forest brush, misc, wood pellets, Wr (willow), Wfc (willow), Ws (willow). Comparison of results based on particle distribution, thermogravimetric, and ultimate and proximate analyses showed significant differences between the examined biomass types.
Additionally, combustion tests in a 120kW multi-fuel boiler revealed also some differences in terms of maximum efficiency, energy conversion efficiency, gaseous emissions and ash residues.This work being focused on the characterization and combustion of olive pomace and below are reported some bibliographic references related to this topic. In 1995, Abu-Qudais 12 studied experimentally the combustion of olive cake in a fluidized bed combustor in taking into account the effects of bed height, fluidization velocity and the biomass flow rate. He showed that the combustion efficiency which was ranging from 86 to 95% increased with air-flow rate. Atimtay and co-workers 13-14 carried out experimental studies on combustion and co-combustion performances and emission characteristics of olive cake and lignite coal.
Their experiments were performed in a circulating fluidized bed (CFB) by using cumulative average particle sizes of d p (d p= 2.3, 0.56 and 0.46 mm) for two categories of biomass. The effect of excess air ratio on the combustion performances is highlighted, and flue gas concentrations of O 2, SO 2, CO 2, CO, NO x and total hydrocarbons were also measured. In reference 13, the use of olive cake and lignite coal mixture (less than 50% of olive cake) for cleaner energy production in small-scale industries, is suggested. As for the pyrolysis and combustion of olive cake, important studies have been conducted by Jauhiainen et al. In reference 15, they identified and quantified the combustion pollutants produced in a laboratory horizontal furnace. They showed that low amounts of pollutants were produced during the thermal treatment, and no dangerous inorganic compounds were detected.
In reference 16, Jauhiainen et al. Have performed dynamic TGA/DTG treatments of olive pomace at heating rates ranging from 5 to 20°C/min. They also proposed a mathematical model to predict pyrolysis and combustion behaviors of this biomass. Miranda et al. 10, 18-19 have also studied the combustion of residues, especially the olive pomace. The properties or characteristics (moisture content, mechanical durability, ash content, calorific value) of the mixture of granulated residues of olive-pomace and Pyrenean oak were analyzed in order to find the best composition to valorize this mixture as a biofuel 10.
Their experiments highlighted that efficient compression of the pellet, improve its handling and transport, without modifying significantly its thermal properties. Furthermore, they used the thermogravimetric analysis (TGA) to illustrate thermal behaviors of olive pomace coming from different olive oil mills 19. The authors concluded that the Concentrated Olive Mill Waste Water (COMWW) is inappropriate for its use in combustion.Several other works concerning the different uses of olive pomace have been published 20-22.
Baccar et al. 20 have prepared the activated carbon from Tunisian olive pomace and its application for the adsorption of heavy metal ions. Encinar et al.
21 conducted the pyrolysis of an olive oil extraction waste with the objective to characterize the char, tar and gaseous phases generated in the process, for their possible use in the energy generation. As for Petrov et al. 22, they investigated and evaluated the quality of the carbon adsorbents produced from olive stones by different methods.In this study, experiments were conducted to predict the potential use of raw olive pomace as a solid biomass fuel. Three samples were characterized, namely, raw olive pomace (R.O.P), exhausted olive pomace (E.O.P) which is pelletized in the cylindrical shape, and deoiled olive pomace (D.O.P) obtained by using Soxhlet extractor 23. Then, two kinds of olive pomace (R.O.P and E.O.P) were burned and their results are compared to those obtained from wood sawdust combustion. Effects of olive pomace particle size on temperature distributions at different combustor device positions were highlighted and the flue gas composition (O 2, CO, CO 2, NO x, SO x) has been measured.
2.1 Experimental deviceThe cylindrical biomass combustor device described in Figure 1 (a) isused for the combustion of raw olive pomace. The experimental setup consists in two vertical compartments: the combustion chamber (fixed-bed reactor), and the flue gas chamber (upper compartment) connected to the chimney by a conical convergent nozzle. In addition, a fuel hopper, a fuel (biomass) feeding system, two blowers, an ash hopper, and a burner hole are also the part of the biomass combustion system. The experimental device is 1500 mm height with a400 mm internal diameter and is made of 6 mm stainless steelthick. A horizontal stainless steel grate with holes of about 1 mm is fixed at the bottom of the combustion chamber. For cooling this experimental prototype, an open loop liquid (water) cooling system is used.
Indeed, water flows inside a copper tube (external heat exchanger) which is coiled around the external wall of two compartments of the biomass experimental setup (Figure 1 (a) and (b)). (b) Positions of thermocouplesFigure 1. Experimental setupPositions of thermocouples are shown in Figure 1 (b). Thus, thermocouples T5 (r=300 mm, z=385 mm) and T10(r=300 mm, z=835 mm) are localized respectively at the upper position of combustion chamber and the upper position of gas flue chamber to control the thermal behavior at the inlet and at the outlet of the gas flue chamber.
Concerning the positions of T6(r=400 mm, z=500 mm) and T8(r=406 mm, z=665 mm), they are respectively placed at the internal wall of gas flue chamber inlet and the external wall of the middle of gas flue chamber in order to quantify the heat loss through combustor wall.2.2 Procedure and instrumentationIn the experiment tests, raw olive pomace is essentially used as a solid fuel which is previously prepared and stored in the fuel hopper. The biomass fuel is fed to the combustion chamber via a worm screw conveyor which is placed below the fuel hopper. This feeding system is calibrated and it is driven by a variable speed motor (SEW-EURODRIVE, r/min: 1380/238) for controlling the mass flow rate of the biomass (16 kg/h in this study). Both air blowers (Forge blower 2.5” inside diameter, 3600 rpm) are turned on to provide a controlled amount of air to the fixed-bed reactor. These instruments were calibrated in advance and the air flow rate is adjusted to appropriate value (101 m 3/h at the blower exit). To ensure uniform distribution of primary air inside the combustion chamber, an object (a half sphere) is placed on the grate center (Figure 1a). Next, the flame was ignited by a gas igniter through the optical portholes, and the combustion chamber was continuously fed by fuel until a stable flame is obtained.
Biomass feeding was done periodically every 90 seconds in average, and three flame portholes were used to observe the progress of combustion. Moreover, there are specific holes along the biomass experimental prototype for temperature measurements (Figure 1a). For this last reason, several K-type thermocouples (Ni/Cr) of 1mm in diameter are located at different high levels from the bottom of the combustion chamber (Figure 1b). After calibratinginstruments, temperature measurements were performed with an accuracy of ±0.05% and then recorded every 30 seconds by using the datalogger (Graphtec GL 220) which has 10 analog input channels for voltage or temperature. For viewing and analyzing results, data are transferred to PC in real-time in a binary (or CSV) format. Close to steady-state condition, a combustion gas analyzer (Kig 300 from Kimo) is connected to the chimney inlet in order to measure the flue gas composition (O 2, CO, CO 2, NO x, SO x).
During the tests, the produced ash is collected in an ash hopper at the bottom of the combustor. Three kinds of biomasses(a) Raw olive pomace,(b) Exhausted olive pomace,(c) Sawdust of woodGenerally, in the case of the biomass, the combustion is influenced by the biomass composition and particle sizes. In fact, for the performed experiments, three average particle sizes (d p) were used for raw olive pomace (Figure 2a), namely, 1mm. 4.1 Effects of particle sizeCombustion tests were performed with discontinuous biomass feeding. To better simulate the real conditions of a semi-industrial unit using biomass to heat water or to produce water steam, the particle sizes of the used biomass have already been indicated. Density of the (R.O.P) has been measured and it is equal to 550 kg/m 3 12, average porosity of fixed bed varies from 0.3 to 0.6, and the initial bed height varies as a term of particle sizes (from 30mm to 100mm).In contrast to several studies deal with different biomasses those have focused on thermal behavior inside the fixed bed 32-35, this study is essentially focused on the thermal attitude on its outside.
Therefore, the locations of the thermocouples take this fact into account (see Figure 1b).The combustion was started by manual ignition at the top layer of the biomass fuel spread on the grate and hence the ignition propagation front moved downwards. After few minutes, the flame was lighting up, temperature measurements have been started.For specified range particle sizes, Figure 5 curves (a, b and c) show the raw olive pomace (R.O.P) temperature distributions versus time at different combustor positions (T5, T6 and T10) above the grate (z=0 mm). Obviously, T5 and T10 could respectively give information on the thermal behavior at the exit of the combustion chamber (first compartment) and at the upper position of the gas flue chamber (second compartment), while T6 coupled with T8 (see Figure 8(a and b)) could help us to evaluate the heat losses through the wall. Before discussing the influence of particle sizes on the combustion process, it is important to explain its mechanism according to these figures (see Figure 5(a, b and c)). Indeed, the three graphical representations highlight two well defined periods during the combustion process, namely, ignition propagation and char oxidation.
It can be seen from these curves (Figure 6(a, b and c)) that, for T5, T6 and T10 positions, temperatures increase rapidly from an initial temperature to a peak value relative to each biomass particle sizes (about 650°C, 440°C and 580°C respectively for each figure at the position T5). Furthermore, when the ignition front is fully developed, the char particles (see Table 1; FC: 20.2% and Ash: 2.8%, and Figures 3, 4(a, b and c)) which are being oxidized covered the upper layer of biomass fuel (R.O.P) at the same time as volatile matters (see Table 1: VM=74.2% and Figures 3, 4(a, b and c)) are burned in the gas phase after having left the packed bed to generate the flame. Another fundamental aspect of the ignition propagation is also the decrease of the temperatures after reaching various peaks because the ignition front propagates downward into the bed against the air flow, and then they rose again to attain other peaks after a new biomass feed. This sawtooth variation (increase/ decrease of temperatures), due to discontinuous biomass feed, persists until the end of the experimental tests reserved for each particle size (see Figure 5(a, b and c)).
Besides, during the ignition period, biomass is represented by four layers which are from the top to the bottom of the fixed bed: Ash, char oxidation, pyrolysis and drying. These last phases are generated by one part of the heat produced by different reactions (char oxidation and gaseous reactions).Now let move from untreated biomass fuel (R.O.P) to pelletized fuel (E.O.P) and sawdust of wood which are the industrial biomasses. It should also be pointed out that, generally, pelletized fuel consists in densifying treated biomass over 600 kg/m 3 32-33 and the sawdust of wood is by-product of sanding wood.
So, Figure 6 (a and b) show the evolution of temperatures at the same positions defined above. These temperatures undergo the same behavior as those corresponding to raw olive pomace (R.O.P) but their magnitudes are much higher.To better understand the effect of particle sizes on thermal behavior outside the fixed bed combustor (Figure 7(a to d)), results are presented according to the positions order put in brackets (T8, T6, T5 and T10). For different biomass fuels used in this study, Figure 7a displays temperature distributions at the external wall designed by T8. It shows clearly the chronological order of experimental tests which are distinguished by the initial temperature. The first three tests relative to (R.O.P) were performed successively without taking time to cool the combustor device, and hence the initial temperatures were respectively 26°C, 107°C and 187 °C. Consequently, these initial values lead to completely mask the granulometry effect on the temperature distributions during the first five minutes (period 1) but for the second period (see Figure 7a) its influence is very obvious. In fact, both curves, which correspond to $2mm.
(b) Sawdust of woodFigure 6. Temperature variations of E.O.P and sawdust of wood versus time at different positions above the grateMoreover, the maximal temperature reaches by (R.O.P) is about 270 °C. As for the sawdust of wood, it heats up more and more the external wall combustor which is in direct contact with the heat exchanger device. Figure 7a shows that the external wall temperature increases with decreasing (R.O.P) particle sizes and hence heat released (see Figure 9 (a and b)) which is a guarantee for supplying the external heat exchanger with heat. This is because a smaller particle size improves the moisture evaporation and char burning rates too. Furthermore, it absorbs radiation flux more quickly and raises the burning rate of volatile gaseous fuel which generates higher temperature values. Note that concluding remarks for Figure 7a, especially for period 2, are also valid for Figure 7(b and c) while Figure 7d behaves a little differently since the temperature of large particles ($20mm≤dp≤30mm$) moves away from that of $2mm.
(c) Average temperature at different position of combustorFigure 8. Effects of particle sizes on different thermal quantitiesDuring period 2 (Figure 8a), it is observed that the effects of biomass types and particle sizes on thermal behavior outside the fixed bed combustor, are confirmed. For the three samples (R.O.P with 1mm. Characterization and combustion of olive pomace in a fixed bed have been done. Three samples were characterized, namely, raw olive pomace (R.O.P), exhausted olive pomace (E.O.P) and deoiled olive pomace (D.O.P). Proximate analysis showed that raw olive pomace (R.O.P) contains volatile matter (74.2%), fixed carbon (20.2%), moisture (7.51%) and ash (2.8%).
As for the ultimate analysis, it highlighted that R.O.P has important content percentages of carbon and oxygen (48.2% and 44.3% respectively). Thermogravimetric analysis showed that in the temperature range 150°C to 400°C, the weight loss corresponding to the burnt volatile matter (VM) is ranging between 65% and 75% for three samples.During combustion process, two well defined phases are identified; namely, ignition propagation and char oxidation. For the first phase and for each biomass, temperatures increase rapidly from an initial temperature to a first peak (about 600 °C) relative to each sample type and particle sizes. The smaller ones allow reaching maximum temporal average temperature and improve the moisture evaporation and char burning rates. Also, they exhibit maximum average flux density in radial direction.The analysis of the combustion gases shows that the emissions of nitrogen oxides (NO x) are very low and sulphur oxides (SO x) ones are practically nil. These are positive results because they are below the pollutant limitation standards.